Creaming (chemistry)

Creaming, in the laboratory sense, is the migration of the dispersed phase of an emulsion, under the influence of buoyancy. The particles float upwards or sink, depending on how large they are and how much less dense or more dense they may be than the continuous phase, and also how viscous or how thixotropic the continuous phase might be. For as long as the particles remain separated, the process is called creaming.

Where it is important that either the form or the concentration of the emulsion should be stable, it is desirable that the continuous and the dispersed phases should have similar densities, and it also is desirable that the continuous phase should be viscous or thixotropic. Thixotropy is particularly valuable in paints, sauces, and similar products, partly because it counteracts tendencies towards creaming. It also is important that the particles be as small as practicable because that reduces their tendency to migrate under the influence of buoyant forces. The electric charges on their surfaces should preferably tend to be uniform, so that the particles repel rather than attract each other.

Creaming is usually seen as undesirable because it causes difficulties in storage and handling, but it can be useful in special cases, especially where it is desirable to concentrate an emulsion. A particular example is in the separation of dairy cream, either to achieve a desired concentration of butterfat, or to make butter. Depending on whether the dispersed particles are less dense or more dense than the continuous phase, they may move either to the top of a sample, or to the bottom. As already stated, the process of migration is called creaming while the particles of the substance remain separated. In this it differs ideally from flocculation (where particles clump) or emulsion breaking (where particles coalesce). One important difference between creaming and the other two processes; unlike flocculation and breaking, creaming of an emulsion is largely a simple process to reverse.

Creaming

A creamed emulsion increases the likelihood of coalescence due to the close proximity of the globules in the cream. Factors that influence the rate of creaming are similar to those involved in the sedimentation rate of suspension particles, and are indicated by Stokes Law.

Creaming of an emulsion also increases the tendency of an emulsion to inversion. This class of process occurs mainly in special cases, when both the continuous and dispersed phases of an emulsion are liquid, as commonly is the state in dairy cream. It is common where the volume of the two fluid components is about the same or the volume of the dispersed phase is larger than that of the continuous phase. The process of emulsion inversion occurs when the dispersed droplets unite, but retain the formerly continuous material as droplets within the mass.

This is an "invert emulsion" or "inverted emulsion", in which the formerly continuous phase has become the dispersed phase and vice versa. Inversion happens in dairy cream when the butterfat concentration is too high, and the resulting invert emulsion looks much like butter.

Commonly invert emulsions look much like a paste or thick cream, and typical examples are mayonnaise, margarine (especially "low-fat" grades of margarine), similar creamy foods, pharmaceutical ointments, and cosmetic "creams".

Emulsion inversion differs from emulsion breaking in that a breaking emulsion tends to separate the two phases into un-emulsified continuous phases. Inversion of an emulsion may or may not be difficult to invert, but generally more difficult than creaming.