Spark plasma sintering

Spark plasma sintering (SPS),[1] also known as field assisted sintering technique (FAST)[2] or pulsed electric current sintering (PECS), is a sintering technique.

The main characteristic of SPS is that the pulsed DC current directly passes through the graphite die, as well as the powder compact, in case of conductive samples. Joule heating has been found to play a dominant role in the densification of powder compacts, which results in achieving near theoretical density at lower sintering temperature compared to conventional sintering techniques.[3] The heat generation is internal, in contrast to the conventional hot pressing, where the heat is provided by external heating elements. This facilitates a very high heating or cooling rate (up to 1000 K/min), hence the sintering process generally is very fast (within a few minutes). The general speed of the process ensures it has the potential of densifying powders with nanosize or nanostructure while avoiding coarsening which accompanies standard densification routes. This has made SPS a good method for preparation of ceramics based on nanoparticles with enhanced piezoelectric,[4] thermoelectric,[5] optical [6] or biomedical [7] properties. SPS is also used for sintering of Carbon Nanotubes [8] for development of field electron emission electrodes. While the term "spark plasma sintering" is commonly used, the term is misleading since neither a spark nor a plasma is present in the process.[9] It has been experimentally verified that densification is facilitated by the use of a current.

A kind of sintering that involves both temperature and pressure

Hybrid heating

By means of a combination of the FAST/SPS method with one or several additional heating systems acting from the outside of the pressing tool systems it's possible to minimize the thermal gradients thus allowing the enhancement of the heating rates at simultaneously optimized homogeneity.[10]

In 2012 the world's largest hybrid SPS-Hot Press sintering system was set up in Spain[11] and the fabrication of fully dense large ceramic blanks of up to 400mm with this system is in progress within the frame of the FP7 European Project HYMACER -HYbrid sintering and advanced Machining of technical CERamics

See also

References

  1. ↑ "Field-Assisted Sintering Technology / Spark Plasma Sintering: Mechanisms,Materials, and Technology Developments", By O. Guillon et al., ADVANCED ENGINEERING MATERIALS 2014, DOI: 10.1002/adem.201300409, http://onlinelibrary.wiley.com/doi/10.1002/adem.201300409/epdf
  2. ↑ KU Leuven - SPS process modeling
  3. ↑ Sairam, K.; Sonber, J.K.; Subramanian, C.; Fotedar, R.K.; Nanekar, P.; Hubli, R.C. "Influence of spark plasma sintering parameters on densification and mechanical properties of boron carbide". International Journal of Refractory Metals and Hard Materials. 42: 185–192. doi:10.1016/j.ijrmhm.2013.09.004.
  4. ↑ Li et al, Ferroelectric and Piezoelectric Properties of Fine-Grained Na0.5K0.5NbO3 Lead-Free Piezoelectric Ceramics Prepared by Spark Plasma Sintering, Journal of the American Ceramic Society, 89, 2, 706–709, (2006)
  5. ↑ Wang; et al. (2006). "High-performance Ag[sub 0.8]Pb[sub 18+x]SbTe[sub 20] thermoelectric bulk materials fabricated by mechanical alloying and spark plasma sintering". Applied Physics Letters. 88: 092104. doi:10.1063/1.2181197.
  6. ↑ Kim; et al. (2007). "Spark plasma sintering of transparent alumina". Scripta Materialia. 57 (7): 607–610. doi:10.1016/j.scriptamat.2007.06.009.
  7. ↑ Gu; et al. (2002). "Spark plasma sintering of hydroxyapatite powders". Biomaterials. 23 (1): 37–43. doi:10.1016/S0142-9612(01)00076-X.
  8. ↑ Talemi; et al. (2012). "Fusion of carbon nanotubes for fabrication of field emission cathodes". Carbon. 50 (2): 356–361. doi:10.1016/j.carbon.2011.07.058.
  9. ↑ Hulbert, D. M.; Anders, A.; Dudina, D. V.; Andersson, J.; Jiang, D.; Unuvar, C.; Anselmi-Tamburini, U.; Lavernia, E. J.; Mukherjee, A. K. (2008). "The absence of plasma in spark plasma sintering". J. Appl. Phys. 104: 033305–7. doi:10.1063/1.2963701.
  10. ↑ M. Suárez, A. Fernández, J.L. Menéndez, R. Torrecillas, H. U. Kessel, J. Hennicke, R. Kirchner and T. Kessel."Challenges and Opportunities for Spark Plasma Sintering: A Key Technology for a New Generation of Materials. Sintering Applications. 2013"
  11. ↑ CINN-CSIC: Hybrid SPS-HP - Photo Gallery
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