Skarn
Skarns or tactites are calcium-bearing calc–silicate rocks. Skarns are most often formed at the contact zone between intrusions of granitic magma bodies and carbonate sedimentary rocks such as limestone and dolostone. Hot waters derived from the granitic magma are rich in silica, iron, aluminium, and magnesium. These fluids mix in the contact zone, dissolve calcium-rich carbonate rocks, and convert the host carbonate rock to skarn deposits in a metamorphic process called metasomatism. The resulting metamorphic rock may consist of a very wide variety of minerals dependent largely on the original composition of the magmatic fluids and the purity of the carbonate sedimentary rocks.
Skarns are sometimes associated with mineable accumulations of metallic ores of iron, copper, zinc, lead, gold, and several others. In such cases these deposits are called "skarn deposits".
Etymology
Skarn is an old Swedish mining term originally used to describe a type of silicate gangue, or waste rock, associated with iron-ore bearing sulfide deposits apparently replacing Palaeoproterozoic age limestones in Sweden's Persberg mining district.[1]
Petrology and types
Skarns are, in their broadest sense, formed by mass and chemical transport and reactions between adjacent rock units. They need not be igneous in origin; two adjacent sedimentary layers such as a banded iron formation and a limestone may react to exchange metals and fluids during metamorphism, creating a skarn.
However, the widest use of the word is in describing the metasomatised zones of wall rock adjacent to granites. Skarns which are created by reaction between metamorphic-sedimentary layers are also known as chemical skarns or skarnoids. Skarns must also be distinguished from calc-silicate hornfels, usually by field relationships.
Skarns of igneous origin are classified as exoskarns or endoskarns. Exoskarns occur at and outside the granite which produced them, and are alterations of wall rocks. Endoskarns, including greisens, form within the granite mass itself, usually late in the intrusive emplacement and consist of cross-cutting stockworks, cooling joints and around the margins and uppermost sections of the granite itself.
Typical skarn minerals include pyroxene, garnet, idocrase, wollastonite, actinolite, magnetite or hematite, and epidote. Because skarns are formed from incompatible-element rich, siliceous aqueous fluids a variety of uncommon mineral types are found in the skarn environment, such as: tourmaline, topaz, beryl, corundum, fluorite, apatite, barite, strontianite, tantalite, anglesite, and others. Often, feldspathoids and rare calc-silicates such as scapolite are found in more marginal areas.
Formation
Skarns are a class of calc–silicate rocks and are intimately associated with granite intrusions, usually of sedimentary-metamorphic origin (S-type). Skarns are rarely seen with other types of granites, because of the fluid chemistry and crystallization behaviour of M-type (mantle origin) and I-type (igneous-metamorphic origin) granites. S-type granites are more prone to generating late-stage fluid rich in silica, incompatible elements and halides because they are generally more potassic, oxidised and hydrous.
Exoskarns are formed when fluids left over from the crystallisation of the granite are ejected from the mass at the waning stages of emplacement. When these fluids come into contact with reactive rocks, usually carbonates such as limestone or dolostone, the fluids react with them, producing alteration (metasomatism).
Because these fluids carry dissolved silica, iron, metals, halides and sulfur, the resulting rock is usually a highly complex combination of calcium, magnesium and carbonate rich minerals.
Uncommon types of skarns are formed in contact with sulfidic or carbonaceous rocks such as black shales, graphite shales, banded iron formations and, occasionally, salt or evaporites. Here, fluids react less via chemical exchange of ions, but because of the redox-oxidation potential of the wall rocks.
Endoskarns are rarer, generally because the fluids created by a granite are usually formed in equilibrium with the minerals of the granite. Endoskarns seem to form in granites which lose earlier, more dilute hydrous fluids, thereby creating a less dilute last spurt of exsolved fluids. Boiling of the exsolved fluid is also considered important, as this creates a highly saline, incompatible-element-rich fluid phase and a highly volatile gas phase.
Ore deposits
Skarns are often hosts for copper, lead, zinc, iron, gold, molybdenum, tin, and tungsten ore deposits. Examples of economic skarn deposits include:
- Pine Creek Mine (tungsten), Inyo County, California, USA
- Ok Tedi Mine (gold and copper), Western Province (Papua New Guinea)
- Avebury Mine (Nickel), Zeehan, Tasmania, (Australia)
See also
References
- ↑ Meinert, L.D, Dipple, G.N., and Nicolescu, S., 2005, "World Skarn Deposits", Economic Geology 100th anniversary volume, p 299-336
- Einaudi M.T., & Burt D.M., 1982. Introduction, terminology, classification and composition of skarn deposits. Economic Geology, 77, pp. 745–754.
- Evans, A.M., 1993. Ore Geology and Industrial Minerals: An Introduction 3rd ed. Blackwell Publishing ISBN 0-632-02953-6
External links
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